Oxidative functionalization of alkylidenecyclopropanes and alkylidenecyclobutanes: a versatile platform to access nitrated cyclopropanes and cyclobutanes-Reference-Cited by-同舟云学术

Oxidative functionalization of alkylidenecyclopropanes and alkylidenecyclobutanes: a versatile platform to access nitrated cyclopropanes and cyclobutanes

Published:2022 Issue:35 Volume:20 Page:7022-7026
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Zeng Yao-Fu¹^ORCID,Wu Jin-Bo¹,Chen Jin-Tao¹,Guo Yu¹^ORCID,Wang Zhen¹^ORCID

Affiliation:

1. School of Pharmaceutical Science, Hunan Provincial Key Laboratory of Tumor Microenvironment Responsive Drug Research, Hengyang Medical School, University of South China, Hengyang, Hunan, 421001, China

Abstract

β-Nitro alcohol, α-nitro ketone and nitro nitratosation compounds were synthesized via radical nitration of alkylidenecyclopropanes and alkylidenecyclobutanes with Fe(NO3)3·9H2O or AgNO2.

Funder

Natural Science Foundation of Hunan Province

Hunan Province Cooperative Innovation Center for Molecular Target New Drug Study

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/OB/D2OB01426B

Reference61 articles.

1. The “Cyclopropyl Fragment” is a Versatile Player that Frequently Appears in Preclinical/Clinical Drug Molecules

2. Put a ring on it: application of small aliphatic rings in medicinal chemistry

3. Ytterbium(III) Triflate-Catalyzed Amination of 1-Cyclopropylprop-2-yn-1-ols as an Expedient Route to Conjugated Enynes

4. Lewis Acid-Catalyzed Ring-Opening Reactions of Methylenecyclopropanes with Alcoholic or Acidic Nucleophiles

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