Discrepancy in the quantitative oxidation-state analysis of Eu species in sulfide phosphors by K-, L1- and L3-edge XANES spectrometry: choice of absorption edge and measurement mode

Author:

Yamamoto Takashi12345ORCID,Yukumoto Akira67895

Affiliation:

1. Department of Natural Science

2. Faculty of Science and Technology

3. Tokushima University

4. Tokushima 770-8506

5. Japan

6. Department of Mathematical and Material Sciences

7. Faculty of Integrated Arts and Sciences

8. University of Tokushima

9. Tokushima 770-8502

Abstract

A quantitative analysis of the oxidation state of europium (Eu) in phosphor samples was performed using X-ray absorption near-edge structure (XANES) spectroscopy to investigate the influence of the constituent elements, absorption edge and measurement mode on the evaluated oxidation states.

Publisher

Royal Society of Chemistry (RSC)

Subject

Spectroscopy,Analytical Chemistry

Reference55 articles.

1. J. Röhler , in Handbook on the Physics and Chemistry of Rare Earths , 1987 , vol. 10 , pp. 453–545 and references cited therein

2. Edge spectroscopy

3. The valence of rare earth ions in R2MgSi2O7:Eu, Dy (R = Ca, Sr) long-afterglow phosphors

4. The valence of Eu under high pressure

5. XANES study of Eu species encapsulated in potassium Y-type zeolite

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