Synthesis and structures of mononuclear and dinuclear gallium complexes with α-diimine ligands: reduction of the metal or ligand?-Reference-Cited by-同舟云学术

Synthesis and structures of mononuclear and dinuclear gallium complexes with α-diimine ligands: reduction of the metal or ligand?

Published:2016 Issue:1 Volume:45 Page:246-252
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Zhao Yanxia¹²³⁴⁵,Liu Yanyan¹²³⁴⁵,Li Qian-Shu⁶⁷⁸⁵,Su Ji-Hu⁹¹⁰¹¹⁵

Affiliation:

1. Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of the Ministry of Education

2. College of Chemistry and Materials Science

3. Northwest University

4. Xi'an 710127

5. China

6. Center for Computational Quantum Chemistry

7. South China Normal University

8. Guangzhou 510631

9. Department of Modern Physics

10. University of Science and Technology of China

11. Hefei 230026

Abstract

A series of gallium complexes with different oxidation states of ligand and metal were obtained, both monoanionic and dianionic ligands can be further reduced, where reduction of the radical monoanionic α-diimine ligand into dianion or of Ga (+3) into the lower oxidation state Ga (+2) or Ga (+1.5) takes place.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C5DT03372A

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4. How Short is a -Ga⋮Ga- Triple Bond? Synthesis and Molecular Structure of Na2[Mes*2C6H3-Ga⋮Ga-C6H3Mes*2] (Mes* = 2,4,6-i-Pr3C6H2): The First Gallyne

5. The Shortest Metal−Metal Bond Yet: Molecular and Electronic Structure of a Dinuclear Chromium Diazadiene Complex

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