Hydrophosphination reactions with transition metal ferrocenylphosphine complexes

Author:

Pritzwald-Stegmann Julian Rodger Frederic12345,Lönnecke Peter12345,Hey-Hawkins Evamarie12345

Affiliation:

1. Institute of Inorganic Chemistry

2. Faculty of Chemistry and Mineralogy

3. Universität Leipzig

4. 04103 Leipzig

5. Germany

Abstract

The group 6 metal mono-, bis- and tris-ferrocenylphosphine complexes [M(CO)5(PH2Fc)], cis-[M(CO)4(PH2Fc)2] and fac-[M(CO)3(PH2Fc)3] (M = Cr, Mo, W; Fc = Fe(η5-C5H4)(η5-C5H5)) were prepared and fully characterised. The coordinated FcPH2 ligand of [W(CO)5(PH2Fc)] undergoes hydrophosphination with alkene substrates bearing EWGs, yielding the corresponding secondary phosphine complexes.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference46 articles.

1. T. B. Rauchfuss , in Homogeneous Catalysis with Metal Phosphine Complexes, ed. L. H. Pignolet, Plenum Press, New York, 1993, ch. 7

2. Phosphorus(III) Ligands in Homogeneous Catalysis: Design and Synthesis, ed. P. C. Kamer and P. W. N. M.van Leeuven, John Wiley & Sons Ltd., UK, 2012

3. A. Behr and P.Neubert, Applied Homogeneous Catalysis, Wiley-VCH Verlag & Co. KGaA, 2012

4. D. E. C. Corbridge , Phosphorus: Chemistry, Biochemistry and Technology, CRC Press, Taylor & Francis Group, Boca Raton, FL, 6th edn, 2013

5. Primary phosphine chemistry

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