Room temperature decarboxylative cyanation of carboxylic acids using photoredox catalysis and cyanobenziodoxolones: a divergent mechanism compared to alkynylation-Reference-Cited by-同舟云学术

Room temperature decarboxylative cyanation of carboxylic acids using photoredox catalysis and cyanobenziodoxolones: a divergent mechanism compared to alkynylation

Published:2017 Issue:3 Volume:8 Page:1790-1800
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Le Vaillant Franck¹²³⁴⁵,Wodrich Matthew D.¹²³⁴⁵^ORCID,Waser Jérôme¹²³⁴⁵^ORCID

Affiliation:

1. Laboratory of Catalysis and Organic Synthesis

2. Institut des Sciences et Ingénierie Chimiques

3. École polytechnique fédérale de Lausanne

4. CH-1015 Lausanne

5. Switzerland

Abstract

Conversion of carboxylic acids to nitriles using photoredox catalysis and benziodoxolone reagents: divergent mechanism when compared to alkynylation!

Funder

European Research Council

École Polytechnique Fédérale de Lausanne

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/SC/C6SC04907A

Reference117 articles.

1. Z. Rappoport , Chemistry of the Cyano Group, Wiley, London, 1970

2. Nitrile-containing natural products

3. Some recent applications of α-amino nitrile chemistry

4. Unsaturated Nitriles: Conjugate Additions of Carbon Nucleophiles to a Recalcitrant Class of Acceptors

5. The synthesis and biological evaluation of novel series of nitrile-containing fluoroquinolones as antibacterial agents

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