One-pot and highly regio-selective 1,3-dipole cycloaddition of azomethine ylide generated in situ to tetraethyl vinylidenebisphosphonate (VBP) catalyzed by cerium(iv) oxide
Author:
Affiliation:
1. Key Laboratory of Tropical Medicinal Plant Chemistry of the Ministry of Education
2. College of Chemistry & Chemical Engineering
3. Hainan Normal University
4. Haikou 571158, P. R. China
Abstract
Higly regio-selective heterocyclic bisphosphonates are obtained in moderate yields (30–70%). The structures of the targeted molecules are characterized by NMR (such as COSY, HSQC, and HMBC), IR and MS.
Publisher
Royal Society of Chemistry (RSC)
Subject
Materials Chemistry,General Chemistry,Catalysis
Link
http://pubs.rsc.org/en/content/articlepdf/2014/NJ/C4NJ00558A
Reference32 articles.
1. Catalytic Enantioselective 1,3-Dipolar Cycloadditions of Azomethine Ylides for Biology-Oriented Synthesis
2. Regio- and Stereoselective Synthesis of Novel Dispiropyrrolidine Bisoxindole Derivatives via Multicomponent Reactions
3. Regioselective Synthesis of Novel Spiropyrrolidines and Spirothiapyrrolizidines Through Multicomponent 1,3-Dipolar Cycloaddition Reaction of Azomethine Ylides
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