The aryne Sommelet–Hauser rearrangement-Reference-Cited by-同舟云学术

The aryne Sommelet–Hauser rearrangement

Published:2019 Issue:20 Volume:55 Page:3004-3007
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Roy Tony¹²³⁴⁵,Gaykar Rahul N.⁶⁷⁸⁴,Bhattacharjee Subrata⁶⁷⁸⁴,Biju Akkattu T.⁶⁷⁸⁴^ORCID

Affiliation:

1. Organic Chemistry Division

2. CSIR-National Chemical Laboratory (CSIR-NCL)

3. Pune 411008

4. India

5. Academy of Scientific and Innovative Research (AcSIR)

6. Department of Organic Chemistry

7. Indian Institute of Science

8. Bangalore-560012

Abstract

An aryne induced transition-metal-free and mild Sommelet–Hauser rearrangement of tertiary benzylamines for the synthesis of α-aryl amino acid derivatives in moderate to good yields and with broad substrate scope is presented.

Funder

Science and Engineering Research Board

Department of Science and Technology, Ministry of Science and Technology

Indian Institute of Science

Council of Scientific and Industrial Research

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2019/CC/C9CC00629J

Reference63 articles.

1. 2-METHYLBENZYLDIMETHYLAMINE

2. Rearrangements of Benzyltrimethylammonium Ion and Related Quaternary Ammonium Ions by Sodium Amide Involving Migration into the Ring1,2,3

3. Rearrangement of 2,4,6-Triisopropylbenzyltrimethylammonium Ion by Sodium Amide to Form an exo-Methylenecyclohexadieneamine and its Reactions1

4. Rearrangement of 2,4,6-Trimethylbenzyltrimethylammonium Ion by Sodium Amide to Form an exo-Methylenecyclohexadieneamine and its Reactions1

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