Molecular complexes and main-chain organometallic polymers based on Janus bis(carbenes) fused to metalloporphyrins-Reference-Cited by-同舟云学术

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Molecular complexes and main-chain organometallic polymers based on Janus bis(carbenes) fused to metalloporphyrins

Published:2020 Issue:21 Volume:49 Page:7005-7014
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Longevial Jean-François¹²³⁴⁵^ORCID,Lo Mamadou¹²³⁴⁵^ORCID,Lebrun Aurélien⁶²⁵⁷,Laurencin Danielle¹²³⁴⁵^ORCID,Clément Sébastien¹²³⁴⁵,Richeter Sébastien¹²³⁴⁵

Affiliation:

1. ICGM

2. Univ Montpellier

3. CNRS

4. ENSCM

5. Montpellier

6. Laboratoire de Mesures Physiques

7. France

Abstract

Janus bis(N-heterocyclic carbenes) composed of a porphyrin core with two N-heterocyclic carbene (NHC) heads fused to opposite pyrroles were used as bridging ligands for the preparation of metal complexes.

Funder

Ministère de l'Education Nationale, de l'Enseignement Superieur et de la Recherche

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/DT/D0DT00594K

Reference61 articles.

1. Carbenes: Synthesis, properties, and organometallic chemistry

2. An overview of N-heterocyclic carbenes

3. Steric and electronic effects in the bonding of N-heterocyclic ligands to transition metals

4. Stability and reactivity of N-heterocyclic carbene complexes

5. Understanding the M(NHC) (NHC=N-heterocyclic carbene) bond

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2. Electrically conductive [Fe₄S₄]-based organometallic polymers;Chemical Science;2023

3. Synthesis and disassembly of an organometallic polymer comprising redox-active Co₄S₄ clusters and Janus biscarbene linkers;Chemical Communications;2022

4. Janus-type homo-, hetero- and mixed valence-bimetallic complexes with one metal encapsulated in a cyclodextrin;Chemical Communications;2022

5. In vitro toxicity and photodynamic properties of porphyrinoids bearing imidazolium salts and N-heterocyclic carbene gold(I) complexes;Comptes Rendus. Chimie;2021-12-16

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