Modular synthesis of oligoacetylacetones via site-selective silylation of acetylacetone derivatives
Author:
Affiliation:
1. Institute for Chemical Reaction Design and Discovery (WPI-ICReDD)
2. Hokkaido University
3. Sapporo
4. Japan
5. Division of Applied Chemistry
6. Faculty of Engineering
Abstract
Aliphatic oligoketones with tailored carbonyl and substituent sequences were modularly synthesized utilizing site-selective formation of enol silyl ethers. Their unique conformational preferences in solid-state were revealed by X-ray crystallography.
Funder
Asahi Glass Foundation
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2020/OB/D0OB00501K
Reference22 articles.
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4. Alternating copolymerization of carbon monoxide and olefins by single-site metal catalysis
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