Reversible coordination of N2 and H2 to a homoleptic S = 1/2 Fe(i) diphosphine complex in solution and the solid state-Reference-Cited by-同舟云学术

Reversible coordination of N2 and H2 to a homoleptic S = 1/2 Fe(i) diphosphine complex in solution and the solid state

Published:2018 Issue:37 Volume:9 Page:7362-7369
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Doyle Laurence R.¹²³⁴,Scott Daniel J.¹²³⁴,Hill Peter J.¹²³⁴,Fraser Duncan A. X.¹²³⁴,Myers William K.⁵⁶⁷⁴^ORCID,White Andrew J. P.¹²³⁴,Green Jennifer C.⁵⁶⁷⁴,Ashley Andrew E.¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. Imperial College London

3. London SW7 2AZ

4. UK

5. Inorganic Chemistry Laboratory

6. University of Oxford

7. Oxford OX1 3QR

Abstract

A 15 valence-electron Fe(i) species rapidly and reversibly binds N₂ and H₂, the latter producing a rare paramagnetic dihydrogen complex.

Funder

Engineering and Physical Sciences Research Council

Royal Society

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/SC/C8SC01841C

Reference40 articles.

1. Catalytic Dinitrogen Fixation to Form Ammonia at Ambient Reaction Conditions Using Transition Metal-Dinitrogen Complexes

2. Recent developments in the homogeneous reduction of dinitrogen by molybdenum and iron

3. Recent developments in synthetic nitrogen fixation

4. Late Metal Scaffolds that Activate Both, Dinitrogen and Reduced Dinitrogen Species NxHy

5. Mechanism of Nitrogen Fixation by Nitrogenase: The Next Stage

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