When water becomes an integral part of carbon – combining theory and experiment to understand the zeolite-like water adsorption properties of porous C2N materials

Author:

Heske Julian12ORCID,Walczak Ralf2,Epping Jan D.3,Youk Sol2,Sahoo Sudhir K.1ORCID,Antonietti Markus2ORCID,Kühne Thomas D.1ORCID,Oschatz Martin24ORCID

Affiliation:

1. Dynamics of Condensed Matter and Center for Sustainable Systems Design, Chair of Theoretical Chemistry, University of Paderborn, Warburger Str. 100, D-33098 Paderborn, Germany

2. Max Planck Institute of Colloids and Interfaces, Colloid Chemistry, Research Campus Golm, Am Mühlenberg 1, D-14476 Potsdam, Germany

3. Fakultät II: Mathematik & Naturwissenschaften, Institut für Chemie, Technische Universität Berlin, Hardenbergstr. 40, D-10623 Berlin, Germany

4. Friedrich-Schiller-University Jena, Institute for Technical Chemistry and Environmental Chemistry, Center for Energy and Environmental Chemistry Jena (CEEC Jena), Philosophenweg 7a, D-07743, Jena, Germany

Abstract

The origin of strong interactions between water molecules and porous C2N surfaces is investigated by using a combination of model materials, volumetric physisorption measurements, solid-state NMR spectroscopy, and DFT calculations.

Funder

Max-Planck-Gesellschaft

European Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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