Nickel-catalysed cycloaddition oligomerisation of 1,6-diynes to medium-size cyclic polyenes-Reference-Cited by-同舟云学术

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Nickel-catalysed cycloaddition oligomerisation of 1,6-diynes to medium-size cyclic polyenes

Published:2022 Issue:43 Volume:13 Page:6127-6133
ISSN:1759-9954
Container-title:Polymer Chemistry
language:en
Short-container-title:Polym. Chem.

Author:

Okabe Yuhsaku¹,Yamada Takeshi¹^ORCID,Okamoto Sentaro¹^ORCID

Affiliation:

1. Department of Materials and Life Chemistry, Kanagawa University, 3-27-1 Rokkakubashi, Kanagawa-ku, Yokohama 221-8686, Japan

Abstract

A nickel-catalysed reaction of 1,6-diynes produced cyclic polyene oligomers with a narrow PDI. Their thermal isomerization gave the regio-isomeric cyclic polyenes consisting of trans-disubstituted alkenes.

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

Link

http://pubs.rsc.org/en/content/articlepdf/2022/PY/D2PY01033J

Reference30 articles.

1. Poly(1,6-heptadiyne)-Based Materials by Metathesis Polymerization

2. Polymerization of Non-conjugated Diynes by Complex Metal Catalysts1,2

3. Poly(1,6-heptadiyne), a free-standing polymer film dopable to high electrical conductivity

4. Cyclopolymerization of dipropargylsilanes by transition-metal catalysts

5. Cyclopolymerization of diethyl dipropargylmalonate by transition metal catalysts

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