Structure and dynamics of Li1.24K0.76CO3 molten carbonate electrolyte from molecular simulations with explicit polarization-Reference-Cited by-同舟云学术

Structure and dynamics of Li_1.24K_0.76CO₃ molten carbonate electrolyte from molecular simulations with explicit polarization

Published:2024 Issue:19 Volume:26 Page:14420-14429
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Sessa Francesco¹²^ORCID,Della Pietra Massimiliano³,Mataloni Simone³,Muñoz-García Ana B.²⁴^ORCID,Pavone Michele¹²^ORCID

Affiliation:

1. Department of Chemical Sciences, Università di Napoli “Federico II”, Compl. Univ. Monte Sant’Angelo, via Cintia 21, 80126, Napoli, Italy

2. National Reference Centre for Electrochemical Energy Storage (GISEL) - INSTM, Via Giusti 9, 50121 Florence, Italy

3. ENEA, R. C. Casaccia, TERIN-PSU-ABI, Via Anguillarese 301, 00123, Rome, Italy

4. Department of Physics “Ettore Pancini”, Università di Napoli “Federico II”, Compl. Univ. Monte Sant’Angelo, via Cintia 21, 80126, Napoli, Italy

Abstract

The structure of the Li1.24K0.76CO3 melt is characterized by a dense network of lithium–carbonate complexes, with K+ ions loosely embedded within this network. This peculiar structure affects the transport properties of the electrolyte.

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CP/D4CP00805G

Reference42 articles.

1. The energy–climate challenge: Recent trends in CO2 emissions from fuel combustion

2. Energy storage technologies and real life applications – A state of the art review

3. Energy storage for mitigating the variability of renewable electricity sources: An updated review

4. Using MCFC for high efficiency CO2 capture from natural gas combined cycles: Comparison of internal and external reforming

5. A numerical and experimental comparison of a single reversible molten carbonate cell operating in fuel cell mode and electrolysis mode