Size and charge effect of guest cations in the formation of polyoxopalladates: a theoretical and experimental study

Author:

Lang Zhongling1234,Yang Peng5678,Lin Zhengguo5678ORCID,Yan Likai910111213ORCID,Li Ming-Xing1415161713,Carbó Jorge J.1234ORCID,Kortz Ulrich5678ORCID,Poblet Josep M.1234ORCID

Affiliation:

1. Departament de Química Física i Inorgànica

2. Universitat Rovira i Virgili

3. 43007 Tarragona

4. Spain

5. Department of Life Sciences and Chemistry

6. Jacobs University

7. 28759 Bremen

8. Germany

9. Institute of Functional Material Chemistry

10. Faculty of Chemistry

11. Northeast Normal University

12. Changchun 130024

13. P. R. China

14. Department of Chemistry

15. College of Sciences

16. Shanghai University

17. Shanghai 200444

Abstract

The close interplay of theoretical and experimental techniques can facilitate the understanding and rational synthesis of novel inorganic clusters, and here an impressive example is shown for the class of cuboid-shaped polyoxo-12-palladates(ii) with a central metal ion guest.

Funder

Institució Catalana de Recerca i Estudis Avançats

Deutsche Forschungsgemeinschaft

Secretaría de Estado de Investigación, Desarrollo e Innovación

Departament d'Innovació, Universitats i Empresa, Generalitat de Catalunya

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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