A ruthenium(ii) bis(phosphinophosphinine) complex as a precatalyst for transfer-hydrogenation and hydrogen-borrowing reactions-Reference-Cited by-同舟云学术

A ruthenium(ii) bis(phosphinophosphinine) complex as a precatalyst for transfer-hydrogenation and hydrogen-borrowing reactions

Published:2017 Issue:19 Volume:46 Page:6172-6176
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Newland R. J.¹²³⁴,Wyatt M. F.⁵⁶⁷⁴,Wingad R. L.⁸⁹¹⁰⁴,Mansell S. M.¹²³⁴^ORCID

Affiliation:

1. Institute of Chemical Sciences

2. Heriot-Watt University

3. Edinburgh

4. UK

5. EPSRC UK National Mass Spectrometry Facility (NMSF)

6. Swansea University Medical School

7. Swansea SA2 8PP

8. School of Chemistry

9. University of Bristol

10. Bristol

Abstract

A Ru(ii) complex with 2-phosphinophosphinine ligands activated with KO^tBu catalyses the room temperature transfer hydrogenation of acetophenone and the hydrogen-borrowing reaction of MeOH/EtOH to the advanced biofuel isobutanol.

Funder

Engineering and Physical Sciences Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/DT/C7DT01022B

Reference65 articles.

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2. Developments in the Coordination Chemistry of Phosphinines

3. Phosphinines as ligands in homogeneous catalysis: recent developments, concepts and perspectives

4. C. Müller and D.Vogt, in Phosphorus Compounds: Advanced Tools in Catalysis and Material Sciences, ed. M. Peruzzini and L. Gonsalvi, 2011, pp. 151–181

5. P-Heterocycles as Ligands in Homogeneous Catalytic Reactions

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