Alkyl–η2-alkene niobocene and tantalocene complexes with the allyldimethylsilyl–η5-cyclopentadienyl ligand: synthesis, NMR studies and DFT calculations-Reference-Cited by-同舟云学术

Alkyl–η2-alkene niobocene and tantalocene complexes with the allyldimethylsilyl–η5-cyclopentadienyl ligand: synthesis, NMR studies and DFT calculations

Published:2004 Issue:18 Volume: Page:2943
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Nicolás Pilar,Royo Pascual,Galakhov Mikhail V.,Blacque Olivier,Jacobsen Heiko,Berke Heinz

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2004/DT/B406747A

Reference56 articles.

1. Models for the Elusive Cp2Zr(R)(olefin)+. Characterization of the d0 Metal Olefin Complex Cp2Zr(OCMe2CH2CH2CH:CH2)+

2. d0 Metal Olefin Complexes. Synthesis, Structures, and Dynamic Properties of (C5R5)2Zr(OCMe2CH2CH2CHCH2)+ Complexes: Models for the Elusive (C5R5)2Zr(R)(Olefin)+ Intermediates in Metallocene-Based Olefin Polymerization Catalysis

3. Measurement of Barriers for Alkene Dissociation and for Inversion at Zirconium in a d0 Zirconium−Alkyl−Alkene Complex

4. Models for Intermediates in Metallocene-Catalyzed Alkene Polymerization: Alkene Dissociation from Cp2Zr[η1,η2-CH2Si(CH3)2CH2CHCH2][B(C6F5)4]

5. Ancillary Ligand and Olefin Substituent Effects on Olefin Dissociation for Cationic Zirconocene Complexes Bearing a Coordinated Pendant Olefin

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