A facile 2H-chromene dimerization through an ortho-quinone methide intermediate catalyzed by a sulfonyl derived MIL-101 MOF-Reference-Cited by-同舟云学术

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A facile 2H-chromene dimerization through an ortho-quinone methide intermediate catalyzed by a sulfonyl derived MIL-101 MOF

Published:2018 Issue:15 Volume:42 Page:12722-12728
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Du Xin¹²³⁴^ORCID,Li Xiujuan¹²³⁴,Tang Houliang⁵⁶⁷⁸,Wang Wenyu⁹¹⁰⁸,Ramella Daniele¹¹¹²⁸,Luan Yi¹²³⁴^ORCID

Affiliation:

1. School of Materials Science and Engineering

2. University of Science and Technology Beijing

3. Beijing 100083

4. P. R. China

5. Department of Chemistry

6. Southern Methodist University

7. Dallas

8. USA

9. The Broad Institute

10. Cambridge

11. Temple University-Beury Hall

12. Philadelphia

Abstract

An efficient homo-dimerization of 2H-chromenes was achieved in high yield and diastereoselectivity using a MIL-101–SO₃H MOF catalyst.

Funder

Natural Science Foundation of Beijing Municipality

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2018/NJ/C8NJ01354C

Reference35 articles.

1. ortho-Quinone Methides in Natural Product Synthesis

2. Taming Reactive Phenol Tautomers and o-Quinone Methides with Transition Metals: A Structure−Reactivity Relationship

3. S. E. Rokita , Quinone Methides , Wiley , Hoboken , 2009

4. Dynamic Cross-Linking Is Retained in Duplex DNA after Multiple Exchange of Strands

5. ortho-Quinone methide (o-QM): a highly reactive, ephemeral and versatile intermediate in organic synthesis

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