Dinitrogen functionalization at a ditantalum center. Balancing N2 displacement and N2 functionalization in the reaction of coordinated N2 with CS2-Reference-Cited by-同舟云学术

Dinitrogen functionalization at a ditantalum center. Balancing N2 displacement and N2 functionalization in the reaction of coordinated N2 with CS2

Published:2018 Issue:24 Volume:47 Page:7983-7991
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Burford Richard J.¹²³⁴,Castro Ludovic⁵⁶⁷⁸⁹,Maron Laurent⁵⁶⁷⁸⁹,Hein Jason E.¹²³⁴^ORCID,Fryzuk Michael D.¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. University of British Columbia

3. Vancouver

4. Canada

5. Universiteé de Toulouse

6. INSA

7. UPS

8. LPCNO

9. F-31077 Toulouse

Abstract

The reaction of CS₂ with the side-on end-on dinitrogen complex ([NPN^Si]Ta)₂(μ–η¹:η²-N₂)(μ-H)₂ generates two products, the ratio of which depends on the concentration of added CS₂.

Funder

Mettler-Toledo

University of British Columbia

Natural Sciences and Engineering Research Council of Canada

Canada Foundation for Innovation

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/DT/C8DT01615A

Reference66 articles.

1. New Approaches to Functionalizing Metal-Coordinated N2

2. Activation and functionalization of molecular nitrogen by metal complexes

3. F. Haber , Nobel Prize Lecture 1918 , in Nobel Lectures, Chemistry 1901–1921 , Elsevier , Amsterdam , 1966

4. C. Bosch , Nobel Prize Lecture 1931 , in Nobel Lectures, Chemistry 1922–1941 , Elsevier , Amsterdam , 1966

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