Tuning the Au–Au interactions by varying the degree of polymerisation in linear polymeric Au(i) N-heterocyclic carbene complexes

Author:

Sathyanarayana Arruri12ORCID,Siddhant Kumar1ORCID,Yamane Masaya1,Hisano Kyohei1ORCID,Prabusankar Ganesan3ORCID,Tsutsumi Osamu1ORCID

Affiliation:

1. Department of Applied Chemistry, Ritsumeikan University, Kusatsu 525-8577, Japan

2. Université Clermont Auvergne, CNRS, SIGMA Clermont, ICCF, F-63000 Clermont-Ferrand, France

3. Department of Chemistry, Indian Institute of Technology Hyderabad, Kandi, TS, 502 285, India

Abstract

Gold(i) N-heterocyclic carbene (Au(i) NHC) polymers were successfully synthesised with alkyl and alkoxy spacers, wherein polymers with different degrees of polymerisation were isolated for the first time by varying the reaction time.

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry

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