Enantioselective Strecker reaction of aldimines using potassium cyanide catalyzed by a recyclable macrocyclic V(v) salen complex-Reference-Cited by-同舟云学术

Enantioselective Strecker reaction of aldimines using potassium cyanide catalyzed by a recyclable macrocyclic V(v) salen complex

Published:2015 Issue:121 Volume:5 Page:99951-99958
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Saravanan S.¹²³⁴⁵,Khan Noor-ul H.¹²³⁴⁵,Jakhar Ajay¹²³⁴⁵,Ansari Amamudin¹²³⁴⁵,Kureshy Rukhsana I.¹²³⁴⁵,Abdi Sayed H. R.¹²³⁴⁵,Kumar Gaurav¹²³⁴⁵

Affiliation:

1. Inorganic Materials and Catalysis Division

2. CSIR-Central Salt and Marine Chemicals Research Institute

3. Bhavnagar-364 002

4. India

5. Academy of Scientific and Innovative Research

Abstract

Chiral dimeric V(v) salen complexes have been synthesized and used as catalysts for asymmetric Strecker reaction of N-benzylimines using both KCN to produce chiral α-amino nitrile. The catalyst was recycled upto five times without loss in its activity.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/RA/C5RA18914D

Reference80 articles.

1. Ueber die künstliche Bildung der Milchsäure und einen neuen, dem Glycocoll homologen Körper;

2. Recent Developments in Catalytic Asymmetric Strecker-Type Reactions

3. Catalytic Enantioselective Strecker Reactions and Analogous Syntheses

4. Recent Developments in the Catalytic Asymmetric Cyanation of Ketimines

5. The Catalytic Asymmetric Strecker Reaction: Ketimines Continue to Join the Fold

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