Mechanistic investigations of alcohol silylation with isothiourea catalysts-Reference-Cited by-同舟云学术

Mechanistic investigations of alcohol silylation with isothiourea catalysts

Published:2021 Issue:46 Volume:19 Page:10181-10188
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Redden Brandon K.¹,Clark Robert W.¹,Gong Ziyuan¹,Rahman Md. Mamdudur¹,Peryshkov Dmitry V.¹^ORCID,Wiskur Sheryl L.¹^ORCID

Affiliation:

1. Department of Chemistry and Biochemistry, University of South Carolina, 631 Sumter St., Columbia, SC 29208, USA

Abstract

The surprising mechanistic results for the silylation of alcohols revealed multiple intermediates and a higher order of silyl chloride leading up to the rate-determining step.

Funder

University of South Carolina

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/OB/D1OB01732B

Reference59 articles.

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2. Kinetic Resolution and Desymmetrization by Stereoselective Silylation of Alcohols

3. Asymmetric Si–O coupling of alcohols

4. Catalytic Silylations of Alcohols: Turning Simple Protecting-Group Strategies into Powerful Enantioselective Synthetic Methods

5. Making the Silylation of Alcohols Chiral: Asymmetric Protection of Hydroxy Groups

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