Dinitrogen cleavage by a dinuclear uranium(<scp>iii</scp>) complex-Reference-Cited by-同舟云学术

Dinitrogen cleavage by a dinuclear uranium(iii) complex

Published:2023 Issue:46 Volume:14 Page:13485-13494
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Jori Nadir¹^ORCID,Keener Megan¹^ORCID,Rajeshkumar Thayalan²,Scopelliti Rosario³^ORCID,Maron Laurent²^ORCID,Mazzanti Marinella¹^ORCID

Affiliation:

1. Insititut des Sciences et Ingénierie Chimiques, Ecole Polytechnique Fédérale de Lausanne (EPFL), 1015 Lausanne, Switzerland

2. Laboratoire de Physique et Chimie des Nano-objets, Institut National des Sciences Appliquées, 31077 Toulouse Cedex 4, France

3. X-Ray Diffraction and Surface Analytics Platform, Institut des Sciences et Ingénierie Chimiques, École Polytechnique Fédérale de Lausanne (EPFL), CH-1015 Lausanne, Switzerland

Abstract

Two dinuclear uranium complexes cooperatively cleave dinitrogen to nitrides in the absence of additional reducing agents probably through a tetranuclear U4(N2)4− intermediate demonstrating the possibility of three-electron transfer from U(iii) to N2.

Funder

Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung

École Polytechnique Fédérale de Lausanne

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/SC/D3SC05253B

Reference46 articles.

1. Mechanism of Nitrogen Fixation by Nitrogenase: The Next Stage

2. Dinitrogen Fixation: Rationalizing Strategies Utilizing Molecular Complexes

3. Activation of Dinitrogen by Polynuclear Metal Complexes

4. Nitrogen Fixation via Splitting into Nitrido Complexes

5. Dinitrogen Cleavage by a Three-Coordinate Molybdenum(III) Complex