Quantum kinetic energy and isotope fractionation in aqueous ionic solutions

Author:

Wang Lu1234ORCID,Ceriotti Michele56789ORCID,Markland Thomas E.1011124ORCID

Affiliation:

1. Department of Chemistry and Chemical Biology

2. Rutgers University

3. Piscataway

4. USA

5. Laboratory of Computational Science and Modeling

6. Institute of Materials

7. École Polytechnique Fédérale de Lausanne

8. 1015 Lausanne

9. Switzerland

10. Department of Chemistry

11. Stanford University

12. Stanford

Abstract

Decomposition of the quantum kinetic energy and isotope fractionation ratios uncovers the local solvation structures in aqueous ionic solutions.

Funder

H2020 European Research Council

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Reference87 articles.

1. J. Hoefs , Stable Isotope Geochemistry , Springer-Verlag Berlin Heidelberg , 2009

2. R. Bradley , Paleoclimatology: Reconstructing Climates of the Quaternary , Academic Press , 2014

3. The Low Barrier Hydrogen Bond in Enzymatic Catalysis

4. Low-Barrier Hydrogen Bonds and Enzymic Catalysis

5. Fractionation factors and activation energies for exchange of the low barrier hydrogen bonding proton in peptidyl trifluoromethyl ketone complexes of chymotrypsin

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