Palladium-catalyzed carbonylation of halo arene-cis-dihydrodiols to the corresponding carboxylates. Access to compounds unavailable by toluene dioxygenase-mediated dihydroxylation of the corresponding benzoate esters
Author:
Affiliation:
1. Chemistry Department and Centre for Biotechnology
2. Brock University
3. St. Catharines, Canada
Abstract
Compounds of high synthetic value were produced in a much more efficient manner than was previously possible through fermentation.
Funder
Natural Sciences and Engineering Research Council of Canada
Canada Research Chairs
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2014/OB/C4OB01417K
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4. The absolute stereochemistry of several cis-dihydrodiols microbially produced from substituted benzenes
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