The importance of chain conformational mobility during 5-exo-cyclizations of C-, N- and O-centred radicals-Reference-Cited by-同舟云学术

The importance of chain conformational mobility during 5-exo-cyclizations of C-, N- and O-centred radicals

Published:2014 Issue:40 Volume:12 Page:7983-7992
ISSN:1477-0520
Container-title:Org. Biomol. Chem.
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Walton John C.¹²³

Affiliation:

1. University of St. Andrews

2. EaStCHEM School of Chemistry

3. Fife, UK

Abstract

The access angle of a radical centre to an alkene acceptor was found to be a key parameter that pinpointed difficult chain reorganizations as responsible for the slow 5-exocyclizations of N-centred radicals.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/OB/C4OB01419G

Reference50 articles.

1. Radicals in Organic Synthesis , ed. P. Renaud and M. P. Sibi , Wiley-VCH , Weinheim , 2001

2. Encyclopedia of Radicals in Chemistry Biology and Materials , ed. C. Chatgilialoglu and A. Studer , Volume 2, Synthetic Strategies and Applications , Wiley , 2012 10.1002/9781119953678 , available online: http://onlinelibrary.wiley.com/book/10.1002/9781119953678 (accessed 21/05/2014)

3. Free radical cyclizations involving nitrogen

4. Radical reactions in natural product synthesis

Cited by 7 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Photoredox Imino Functionalizations of Olefins;Angewandte Chemie International Edition;2017-09-22

2. Photoredox Imino Functionalizations of Olefins;Angewandte Chemie;2017-09-22

3. Radical Reaction Control in the AdoMet Radical Enzyme CDG Synthase (QueE): Consolidate, Destabilize, Accelerate;Chemistry - A European Journal;2016-12-13

4. The Baldwin rules: revised and extended;Wiley Interdisciplinary Reviews: Computational Molecular Science;2016-04-27

5. Functionalised Oximes: Emergent Precursors for Carbon-, Nitrogen- and Oxygen-Centred Radicals;Molecules;2016-01-07