l-Lactide polymerization catalysed by tin(ii) 2-ethyl-hexanoate. A deeper look at chain transfer reactions-Reference-Cited by-同舟云学术

l-Lactide polymerization catalysed by tin(ii) 2-ethyl-hexanoate. A deeper look at chain transfer reactions

Published:2015 Issue:35 Volume:6 Page:6292-6296
ISSN:1759-9954
Container-title:Polymer Chemistry
language:en
Short-container-title:Polym. Chem.

Author:

Sosnowski Stanislaw¹²³,Lewinski Piotr¹²³

Affiliation:

1. Centre of Molecular and Macromolecular Studies Polish Academy of Sciences

2. 90-363 Lodz

3. Poland

Abstract

Segmental exchange reactions inl-lactide polymerization catalysed by tin octoate yield chains with even and odd numbers of lactoyl units. The efficiency of the reactions depends on the position of the attacked unit in the chain. The terminal units are at least 100 times more reactive than others.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

Link

http://pubs.rsc.org/en/content/articlepdf/2015/PY/C5PY00748H

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