Copper ligand and anion effects: controlling the kinetics of the photoinitiated copper(i) catalyzed azide—alkyne cycloaddition polymerization
Author:
Affiliation:
1. Department of Chemical and Biomolecular Engineering
2. University of Delaware
3. Newark
4. USA
5. Department of Materials Science and Engineering
Abstract
The kinetic performance of amine-based ligands and counter anions on the copper(ii) catalyst in photoinduced-CuAAC reactions is explored.
Funder
National Institute of Dental and Craniofacial Research
National Institute of General Medical Sciences
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering
Link
http://pubs.rsc.org/en/content/articlepdf/2018/PY/C8PY01004H
Reference59 articles.
1. A Stepwise Huisgen Cycloaddition Process: Copper(I)-Catalyzed Regioselective “Ligation” of Azides and Terminal Alkynes
2. Peptidotriazoles on Solid Phase: [1,2,3]-Triazoles by Regiospecific Copper(I)-Catalyzed 1,3-Dipolar Cycloadditions of Terminal Alkynes to Azides
3. Click Chemistry: Diverse Chemical Function from a Few Good Reactions
4. The growing impact of click chemistry on drug discovery
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