Carbene-like reactivity of methoxy groups in a single crystal SAPO-34 MTO catalyst-Reference-Cited by-同舟云学术

Carbene-like reactivity of methoxy groups in a single crystal SAPO-34 MTO catalyst

Published:2022 Issue:7 Volume:12 Page:2289-2305
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Minova Ivalina B.¹,Bühl Michael¹^ORCID,Matam Santhosh K.²³^ORCID,Catlow C. Richard A.²³⁴,Frogley Mark D.⁵,Cinque Gianfelice⁵^ORCID,Wright Paul A.¹^ORCID,Howe Russell F.⁶^ORCID

Affiliation:

1. EastCHEM School of Chemistry, University of St Andrews, St Andrews KY16 9ST, UK

2. UK Catalysis Hub, Research Complex at Harwell, Rutherford Appleton Laboratory, Oxford, OX11 0FA, UK

3. Cardiff Catalysis Institute, School of Chemistry, Cardiff University, Cardiff CF10 3AT, UK

4. Department of Chemistry, University College London, London WC1E 6BT, UK

5. MIRIAM beamline B22, Diamond Light Source, Harwell Science and Innovation Campus, Didcot, OX11 0DE, UK

6. Chemistry Department, University of Aberdeen, AB24 3UE, UK

Abstract

In situ synchrotron infrared microspectroscopy on single crystals of SAPO-34 reveals that a carbene insertion mechanism is responsible for the first carbon–carbon bond formation from surface methoxy groups.

Funder

Engineering and Physical Sciences Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CY/D1CY02361F

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