Electricity-driven 1,4-alkoxydimerization of alkenes via radical–polar crossover

Author:

Tan Yu-Fang1ORCID,Yang Dan1,Yang Yu-Hao1,Lv Jin-Feng1,Zong Lan-Xi1,Guan Zhi1ORCID,He Yan-Hong1ORCID

Affiliation:

1. Key Laboratory of Applied Chemistry of Chongqing Municipality, School of Chemistry and Chemical Engineering, Southwest University, Chongqing 400715, China

Abstract

A variety of readily available (hetero)aryl alkenes and (halo)aliphatic alcohols can be used in the reaction to produce 1,4-dialkoxybutanes. The only by-product of the reaction is H2, making the method clean and highly atom-economical.

Funder

National Natural Science Foundation of China

Southwest University

Graduate School, Chongqing University

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

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