UV-visible spectroscopy of macrocyclic alkyl, nitrosyl and halide complexes of cobalt and rhodium. Experiment and calculation-Reference-Cited by-同舟云学术

UV-visible spectroscopy of macrocyclic alkyl, nitrosyl and halide complexes of cobalt and rhodium. Experiment and calculation

Published:2015 Issue:8 Volume:44 Page:3811-3816
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Hull Emily A.¹²³⁴,West Aaron C.¹²³⁴,Pestovsky Oleg¹²³⁴,Kristian Kathleen E.¹²³⁴,Ellern Arkady¹²³⁴,Dunne James F.¹²³⁴,Carraher Jack M.¹²³⁴,Bakac Andreja¹²³⁴,Windus Theresa L.¹²³⁴

Affiliation:

1. Department of Chemistry and Ames Laboratory

2. Iowa State University

3. Ames

4. USA

Abstract

Visible light photolysis of Co(NH₃)₅CH₃²⁺ generates alkyl radicals, unlike the halide complexes Co(NH₃)₅X²⁺ which produce halogen anions, X⁻.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C4DT03143A

Reference40 articles.

1. Visible Light‐Induced Release of Nitrogen Monoxide from a Nitrosylrhodium Complex

2. E. Zinato , in Concepts of Inorganic Photochemistry, ed. A. W. Adamson and P. D. Fleischauer, Wiley, New York, 1975

3. The photochemistry of organocobalt complexes containing tetraaza macrocyclic ligands. Cobalt-methyl homolysis and the nature of the cobalt-carbon bond

4. Photophysical and photochemical properties of rhodium(III) halopentaammine complexes in aqueous solution. Reaction kinetics of ligand field excited states

5. Ligand field photochemistry of halopentaamminerhodium(III) complexes

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