An experimental and theoretical investigation of the N(2D) + C6H6 (benzene) reaction with implications for the photochemical models of Titan-Reference-Cited by-同舟云学术

An experimental and theoretical investigation of the N(²D) + C₆H₆ (benzene) reaction with implications for the photochemical models of Titan

Published:2023 Issue: Volume:245 Page:327-351
ISSN:1359-6640
Container-title:Faraday Discussions
language:en
Short-container-title:Faraday Discuss.

Author:

Balucani Nadia¹^ORCID,Caracciolo Adriana¹,Vanuzzo Gianmarco¹^ORCID,Skouteris Dimitrios²^ORCID,Rosi Marzio³^ORCID,Pacifici Leonardo¹,Casavecchia Piergiorgio¹^ORCID,Hickson Kevin M.⁴^ORCID,Loison Jean-Christophe⁴^ORCID,Dobrijevic Michel⁵

Affiliation:

1. Dipartimento di Chimica, Biologia e Biotecnologie, Università degli Studi di Perugia, 06123 Perugia, Italy

2. Master-Tec SrL, Via Sicilia, 41, 06128 Perugia, Italy

3. Dipartimento di Ingegneria Civile e Ambientale, Università degli Studi di Perugia, 06100, Perugia, Italy

4. Univ. Bordeaux, CNRS, Bordeaux INP, ISM, UMR 5255, F-33400 Talence, France

5. Univ. Bordeaux, CNRS, LAB, UMR 5804, F-33600 Pessac, France

Abstract

Low temperature kinetics, crossed beam experiments, calculations of the underlying potential energy surface and of the product branching fractions for the N(2D) + benzene reaction are reported. The results have been used in a photochemical model of Titan.

Funder

Agenzia Spaziale Italiana

Università degli Studi di Perugia

Centre National d’Etudes Spatiales

Commissariat à l’Énergie Atomique et aux Énergies Alternatives

Institut national des sciences de l’Univers

Institut de physique

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/FD/D3FD00057E

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4. Elementary reactions of N atoms with hydrocarbons: first steps towards the formation of prebiotic N-containing molecules in planetary atmospheres

5. Variability in Titan’s Mesospheric HCN and Temperature Structure as Observed by ALMA

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