Energy band alignment at the heterointerface between a nanostructured TiO2 layer and Au22(SG)18 clusters: relevance to metal-cluster-sensitized solar cells

Author:

Larina Liudmila L.12345,Omelianovych Oleksii1234,Dao Van-Duong1234ORCID,Pyo Kyunglim6784,Lee Dongil6784ORCID,Choi Ho-Suk1234ORCID

Affiliation:

1. Department of Chemical Engineering and Applied Chemistry

2. Chungnam National University

3. Daejeon

4. Republic of Korea

5. Department of Solar Photovoltaics

6. Department of Chemistry

7. Yonsei University

8. Seoul 03722

Abstract

XPS study of the electronic structure of the Au22(SG)18 clusters and their interface with TiO2 reveals that tailoring of the electronic band structure at the interface can be exploited to increase the efficiency of metal-cluster-sensitized solar cells.

Funder

National Research Foundation of Korea

Russian Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science

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