σ-Holes and σ-lumps direct the Lewis basic and acidic interactions of noble metal nanoparticles: introducing regium bonds
Author:
Affiliation:
1. Applied Physical Chemistry
2. School of Chemical Science and Engineering
3. KTH Royal Institute of Technology
4. Stockholm
5. Sweden
6. Swedish Nuclear Fuel and Waste Management Company (SKB)
7. Solna
Abstract
Using local DFT-based probes for electrostatic as well as charge transfer/polarization interactions, we are able to characterize Lewis basic and acidic sites on copper, silver and gold nanoparticles.
Funder
Kungliga Tekniska Högskolan
Svensk Kärnbränslehantering
Publisher
Royal Society of Chemistry (RSC)
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy
Link
http://pubs.rsc.org/en/content/articlepdf/2018/CP/C7CP06259A
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