Nanostructuring determines poisoning: tailoring CO adsorption on PtCu bimetallic nanoparticles

Author:

Vega Lorena12ORCID,Garcia-Cardona Julia1,Viñes Francesc12ORCID,Cabot Pere L.1ORCID,Neyman Konstantin M.123ORCID

Affiliation:

1. Departament de Ciència de Materials i Química Física, Universitat de Barcelona, c/Martí i Franquès 1-11, 08028 Barcelona, Spain

2. Institut de Química Teòrica i Computacional (IQTCUB), Universitat de Barcelona, c/Martí i Franquès 1-11, 08028 Barcelona, Spain

3. ICREA (Institució Catalana de Recerca i Estudis Avançats), Pg. Lluís Companys 23, 08010 Barcelona, Spain

Abstract

A combination of CO stripping voltammograms on diverse PtCu nanoparticles fuel cell electrocatalysts and density functional calculations show that surface chemical ordering and certain defects presence explain the CO tolerance vs. poisoning.

Funder

Ministerio de Ciencia, Innovación y Universidades

Agencia Estatal de Investigación

Generalitat de Catalunya

Ministerio de Economía y Competitividad

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Chemistry (miscellaneous)

Reference58 articles.

1. D.Thompsett , Pt Alloys as Oxygen Reduction Catalysts. Handbook of Fuel Cells. Fundamentals, Technology and Applications , John Wiley & Sons , 2003 , New York

2. M. K.Mahapatra and P.Singh , Fuel Cells: Energy Conversion Technology, Future Energy: Improved, Sustainable and Clean Options for our Planet , Elsevier , 2014 , London

3. Electrocatalyst approaches and challenges for automotive fuel cells

4. A comprehensive review of Pt electrocatalysts for the oxygen reduction reaction: Nanostructure, activity, mechanism and carbon support in PEM fuel cells

5. K.Ruth , M.Vogt and R.Zuber , Development of CO-Tolerant Catalysts on Pt/Ru Catalysts , John Wiley & Sons , 2010 , New York

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