Polynuclear titanocene complexes with antimony ligands: [(Cp2Ti)2(SbR2)2] (R = Et), [(Cp2Ti)3(SbR)3Sb] [R = 2-(Me2NCH2)C6H4] and [(Cp2Ti)5(SbR)2Sb7] (R = Me3SiCH2)
Author:
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2009/DT/B904846D
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1. Synthesis and chemical properties of dicyclopentadienylzirconium bis(diphenylarsenide) and bis(diphenylantimonide), [(η-C5H5)2Zr(EPh2)2] (E = As OR Sb)
2. Catalytic Antimony–Antimony Bond Formation through Stibinidene Elimination from Zirconocene and Hafnocene Complexes
3. Antimony−Antimony Bond Formation by Reductive Elimination from a Hafnium Bis(stibido) Complex
4. Terminal stibinidene ligands. Generation of CpCp*HfSb(dmp) and trapping reactions with PMe3and 2-butyne
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