Visible and near-infrared emitting heterotrimetallic lanthanide–aluminum–sodium 12-metallacrown-4 compounds: discrete monomers and dimers-Reference-Cited by-同舟云学术

Visible and near-infrared emitting heterotrimetallic lanthanide–aluminum–sodium 12-metallacrown-4 compounds: discrete monomers and dimers

Published:2022 Issue:15 Volume:51 Page:5989-5996
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Eliseeva Svetlana V.¹^ORCID,Travis Jordan R.²,Nagy Sarah G.²,Smihosky Alyssa M.²,Foley Collin M.²,Kauffman Abigail C.²,Zaleski Curtis M.²^ORCID,Petoud Stéphane¹^ORCID

Affiliation:

1. Centre de Biophysique Moléculaire, CNRS UPR 4301, 45071 Orléans Cedex 2, France

2. Department of Chemistry and Biochemistry, Shippensburg University, 1871 Old Main Dr., Shippensburg, PA 17257, USA

Abstract

The terbium-aluminum metallacrowns (MC), TbAl4Na (left image & capillary) and Tb2Al8Na2 (right image & capillary) emit green light. Tb2Al8Na2 has a quantum yield value of 43.9%, the highest value observed in the solid state to date for a TbIII MC.

Funder

Faculty Professional Development Council, Pennsylvania State System of Higher Education

Ligue Contre le Cancer

Cancéropôle Grand Ouest

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/DT/D1DT04277G

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