DFT study on the redox behavior of two dioxovanadium(v) complexes with N2O donor Schiff base ligands and their use in catalytic oxidation ofortho-aminophenol-Reference-Cited by-同舟云学术

DFT study on the redox behavior of two dioxovanadium(v) complexes with N2O donor Schiff base ligands and their use in catalytic oxidation ofortho-aminophenol

Published:2019 Issue:47 Volume:43 Page:18747-18759
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Thakur Snehasish¹²³⁴,Banerjee Snehasis⁵⁶⁷⁴,Das Saurabh¹²³⁴^ORCID,Chattopadhyay Shouvik¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. Jadavpur University

3. Kolkata-700032

4. India

5. Govt. College Of Engineering and Leather Technology

6. Salt Lake Sector-III, Block-LB

7. Kolkata-106

Abstract

Solution phase redox behavior of two vanadium(v) Schiff base complexes was checked. The results agree well with DFT calculations. Both complexes exhibited good catalytic efficiency for the conversion ofo-aminophenol to 2-aminophenoxazine-3-one.

Funder

Department of Science and Technology, Ministry of Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2019/NJ/C9NJ04672K

Reference90 articles.

1. Coordination chemistry of vanadium in biological systems

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3. Ferromagnetic oxovanadium(IV) complexes chelated with tetrahalosalen ligands