Desymmetrization of disubstituted aromatic crown ethersviaintramolecular Cannizzaro reactions-Reference-Cited by-同舟云学术

Desymmetrization of disubstituted aromatic crown ethersviaintramolecular Cannizzaro reactions

Published:2019 Issue:43 Volume:43 Page:16801-16805
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Rouser Mason A.¹²³⁴,Gibson Harry W.¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. Virginia Tech

3. Blacksburg

4. USA

Abstract

Ba⁺⁺templated Cannizzaro reactions convert symmetrical aromatic crown ether dialdehydes of various types [dibenzo and bis(meta-phenylene)] and sizes (20–32 atom rings) to acid–alcohol functionalized crown ethers in 70–98% yields.

Funder

American Chemical Society Petroleum Research Fund

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2019/NJ/C9NJ04679H

Reference42 articles.

1. Cyclic polyethers and their complexes with metal salts

2. Cyclic polyethers and their complexes with metal salts

3. New Macrocyclic Polyethers

4. MACROCYCLIC POLYETHERS: DIBENZO-18-CROWN-6 POLYETHER AND DICYCLOHEXYL-18-CROWN-6 POLYETHER

5. Crystal Structure of a Cyclic Polyether Complex of Alkali Metal Thiocyanate

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2. A metal–carbene template approach enables efficient synthesis of a functionalized cage-annulated crown ether;Chemical Communications;2021

3. Eight-membered and larger rings;Progress in Heterocyclic Chemistry;2021

4. Correction: Desymmetrization of disubstituted aromatic crown ethers via intramolecular Cannizzaro reactions;New Journal of Chemistry;2019