Copper-assisted trifluoromethylthiolation/radical cascade cyclization of alkynes to construct SCF<sub>3</sub>-containing dioxodibenzothiazepines-Reference-Cited by-同舟云学术

Copper-assisted trifluoromethylthiolation/radical cascade cyclization of alkynes to construct SCF₃-containing dioxodibenzothiazepines

Published:2022 Issue:62 Volume:58 Page:8674-8677
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Chen Xiaoyu¹,Pei Congcong¹,Liu Bo¹,Li Jingya²,Zou Dapeng¹,Wu Yangjie¹^ORCID,Wu Yusheng¹³^ORCID

Affiliation:

1. College of Chemistry, Green Catalysis Center, Zhengzhou University, Zhengzhou, Henan, 450001, People's Republic of China

2. Tetranov Biopharm, LLC., Zhengzhou, 450052, People's Republic of China

3. Tetranov International, Inc., 100 Jersey Avenue, Suite A340, New Brunswick, NJ, 08901, USA

Abstract

A mild and efficient Cu-assisted trifluoromethylthiolation/radical cascade cyclization of alkynes with readily available and stable AgSCF3 as the trifluoromethylthiolating reagent has been disclosed.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CC/D2CC02171D

Reference71 articles.

1. Fluorinated organic materials for electronic and optoelectronic applications: the role of the fluorine atom

2. Fluorine in medicinal chemistry

3. Fluorine and Fluorinated Motifs in the Design and Application of Bioisosteres for Drug Design

4. Visible-Light-Induced Regio- and Stereoselective C(sp2)–H Trifluoroethylation of Enamides with 2,2,2-Trifluoroethyl Iodide

5. Regioselective and Stereoselective Difluoromethylation of Enamides with Difluoromethyltriphenylphosphonium Bromide via Photoredox Catalysis

Cited by 14 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. AgSCF3 Radical Addition Based on an Oxidant-Free α,β-Amide (Trifluoromethyl)sulfanylation Reaction;Synlett;2024-04-18

2. Iron‐Catalyzed Direct C3−H Trifluoromethylthiolation of Quinoxalin‐2(1H)‐ones;Advanced Synthesis & Catalysis;2023-12-20

3. Visible‐Light‐Induced Multicomponent Reaction of Aromatic Aldehydes, Amines and Sodium Difluoromethanesulfinate: Synthesis of CF₂H‐Substituted Secondary Amines;Advanced Synthesis & Catalysis;2023-10-18

4. Photoinduced Tandem Cyanomethylation/Cyclization of Unsaturated Compounds: Access to Cyanomethylated 7- or 5-Membered N-Heterocycles;The Journal of Organic Chemistry;2023-08-02

5. Cascade Radical Trifluoromethylthiolation/Cyclization of Dienes To Access SCF₃-Containing Medium-Sized Heterocycles;Organic Letters;2023-06-12