Effects of partial isovalent substitution of V with (Ti,Fe) on redox reactivity in Li<sub>2</sub>VO<sub>2</sub>F battery cathodes-Reference-Cited by-同舟云学术

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Effects of partial isovalent substitution of V with (Ti,Fe) on redox reactivity in Li₂VO₂F battery cathodes

Published:2024 Issue:23 Volume:12 Page:13852-13859
ISSN:2050-7488
Container-title:Journal of Materials Chemistry A
language:en
Short-container-title:J. Mater. Chem. A

Author:

Hirsbrunner Moritz¹^ORCID,Källquist Ida¹^ORCID,Kullgren Jolla²^ORCID,Rensmo Håkan¹^ORCID,Hahlin Maria¹²^ORCID,Duda Laurent C.¹^ORCID

Affiliation:

1. Department of Physics and Astronomy, Division of Molecular and Condensed Matter Physics, Uppsala University, Box 516, 751 20 Uppsala, Sweden

2. Department of Chemistry – Ångström Laboratory, Uppsala University, Box 523, 751 20 Uppsala, Sweden

Abstract

The influence of substitution of V with Fe or Ti in the Li-rich battery cathode material Li2VO2F was investigated utilizing XAS and RIXS to obtain bulk sensitive information about electronic structure changes.

Funder

Stand Up for Energy

Energimyndigheten

Vetenskapsrådet

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/TA/D3TA05916B

Reference35 articles.

1. Li+ intercalation in isostructural Li2VO3 and Li2VO2F with O2− and mixed O2−/F− anions

2. Disordered Lithium-Rich Oxyfluoride as a Stable Host for Enhanced Li+Intercalation Storage

3. Improved cycling stability in high-capacity Li-rich vanadium containing disordered rock salt oxyfluoride cathodes

4. Degradation Mechanisms in Li2VO2F Li-Rich Disordered Rock-Salt Cathodes

5. Structural Characterization of the Delithiated Noncrystalline Phase in a Li-Rich Li2VO2F Cathode Material

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