Diastereomerically pure rarely functionalized alkenoyl dihydropyrans, 1,6-diketones, and cyclopentanes from acetylene gas and ketones-Reference-Cited by-同舟云学术

Diastereomerically pure rarely functionalized alkenoyl dihydropyrans, 1,6-diketones, and cyclopentanes from acetylene gas and ketones

Published:2022 Issue:33 Volume:20 Page:6593-6605
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Tatarinova Inna V.¹^ORCID,Lobanova Natal'ya A.¹^ORCID,Ushakov Igor’ A.¹,Schmidt Elena Yu.¹,Trofimov Boris A.¹^ORCID

Affiliation:

1. A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences 1 Favorsky Str., 664033 Irkutsk, Russia

Abstract

Alkenoyl dihydropyrans stereoselectively assembled from acetylene gas, ketones and aldehydes in two steps are diastereoselectively transformed into difficult-to-access, rarely functionalized 1,6-diketones and cyclopentanes.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/OB/D2OB01068B

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