The construction of phosphonate triazolyl by copper(<scp>ii</scp>)-catalyzed furan dearomatized [3 + 2] cycloaddition-Reference-Cited by-同舟云学术

The construction of phosphonate triazolyl by copper(ii)-catalyzed furan dearomatized [3 + 2] cycloaddition

Published:2022 Issue:32 Volume:20 Page:6319-6323
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Wahab Abdul¹,Gao Ziwei¹^ORCID,Gou Jing²^ORCID,Yu Binxun¹³^ORCID

Affiliation:

1. Key Laboratory of Applied Surface and Colloid Chemistry, Ministry of Education, School of Chemistry & Chemical Engineering, Shaanxi Normal University, Xi'an 710062, China

2. Shaanxi Key Laboratory for Advanced Energy Devices, Shaanxi Normal University, Xi'an 710062, China

3. SCNU Qingyuan Institute of Science and Technology Innovation Co., Ltd., Qingyuan 511517, China

Abstract

Synthesis of triazolyl phosphonates, valuable structural motifs in chemical biology, starting from furfuryl phosphonate alcohols and organo-azides, using an intermolecular copper-catalyzed dearomatized [3 + 2] cycloaddition/furan ring-opening cascade reaction.

Funder

Natural Science Basic Research Program of Shaanxi Province

Science and Technology Planning Project of Guangdong Province

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/OB/D2OB01060G

Reference49 articles.

1. Rhodium(I)-Catalyzed Azide-Alkyne Cycloaddition (RhAAC) of Internal Alkynylphosphonates with High Regioselectivities under Mild Conditions