Novel approach for the synthesis of chiral organometallic complexes – first series of lithium 2-amino-indenide ligands bearing pendant donor groups and a unique helical bent-zirconocene-Reference-Cited by-同舟云学术

Novel approach for the synthesis of chiral organometallic complexes – first series of lithium 2-amino-indenide ligands bearing pendant donor groups and a unique helical bent-zirconocene

Published:2022 Issue:3 Volume:46 Page:1409-1415
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Rufanov Konstantin A.¹^ORCID,Titov Ilya Yu.²³,Lemenovskii Dmitry A.⁴,Krut’ko Dmitry P.⁴,Churakov Andrei V.⁵^ORCID

Affiliation:

1. Institute of Living Systems, I. Kant Baltic Federal University, Kaliningrad 236040, Russian Federation

2. N.D. Zelinsky-Institute of Organic Chemistry, Russian Academy of Sciences, Leninsky prospect, 47, Moscow 119991, Russian Federation

3. HSE University, Myasnitskaya ulitsa, 20, Moscow 101000, Russian Federation

4. Department of Chemistry, M.V. Lomonosov State University of Moscow, Moscow 119991, Russian Federation

5. N.S. Kurnakov-Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskiy prospect., 31, Moscow 119991, Russian Federation

Abstract

Direct metallation of chiral 2-amino-indenyl ligands leads to a lithiated species linked in infinite chains and a unique helical bent zirconocene.

Funder

Philipps-Universität Marburg

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/NJ/D1NJ05094J

Reference27 articles.

1. Preparation of Some N-Substituted 2-Aminoindanes.

2. Stabilised enamine anions. Generation and alkylation of anions stabilised as cyclopentadienide enamine systems

3. Aminocyclopentadienes, Aminoferrocenes, and Aminocobaltocenes

4. Syntheses and X-Ray Crystal Structures of 2-Aminoindenes and Aminocymantrenes

5. Aminoferrocenes and Aminocobaltocenes as Redox-Active Chelating Ligands: Syntheses, Structures, and Coordination Chemistry1

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