C(sp3)–H bond activation by the carboxylate-adduct of osmium tetroxide (OsO4)-Reference-Cited by-同舟云学术

登录注册会员服务联系我们

C(sp3)–H bond activation by the carboxylate-adduct of osmium tetroxide (OsO4)

Published:2022 Issue:3 Volume:51 Page:1123-1130
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Fujimoto Tomohiro¹,Hirata Yuka¹,Sugimoto Hideki¹^ORCID,Miyanishi Mayuko²,Shiota Yoshihito²,Yoshizawa Kazunari²^ORCID,Itoh Shinobu¹^ORCID

Affiliation:

1. Department of Molecular Chemistry, Division of Applied Chemistry, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871, Japan

2. Institute for Material Chemistry and Engineering and International Research Center for Molecular System, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka, 819-0395, Japan

Abstract

The carboxylate adducts of OsO4 ([OsO4(X)]−, X− = AcO− and BzO−) were isolated and their structures, physicochemical properties and reactivity were explored. The C(sp3)−H oxygenation mechanism by the carboxylate adducts was discussed based on their kinetics and DFT studies.

Funder

Japan Society for the Promotion of Science

Core Research for Evolutional Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/DT/D1DT03819B

Reference36 articles.

1. Catalytic Asymmetric Dihydroxylation

2. Asymmetric Aminohydroxylation

3. Osmium-Catalyzed Oxidative Cyclization of Dienes and Their Derivatives

4. The Hydroxylation of the Double Bond1

5. New reaction. Stereospecific vicinal oxyamination of olefins by alkyl imido osmium compounds

Cited by 4 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. 金属– 酸化活性種の創出と機能解明;Bulletin of Japan Society of Coordination Chemistry;2023-05-31

2. Ru(iv)–Ru(iv) complexes having the doubly oxido-bridged core with a bridging carbonato or hydrogencarbonato ligand;Dalton Transactions;2023

3. Recent progress in oxidation chemistry of high-valent ruthenium-oxo and osmium-oxo complexes and related species;Coordination Chemistry Reviews;2022-09

4. Alkane Oxidation with H₂O₂ Catalyzed by OsO₄-carboxylate Adduct and Its Application to Heterogeneous Catalyst;Chemistry Letters;2022-03-05

同舟云学术

1.学者识别学者识别

2.学术分析学术分析

3.人才评估人才评估

"同舟云学术"是以全球学者为主线，采集、加工和组织学术论文而形成的新型学术文献查询和分析系统，可以对全球学者进行文献检索和人才价值评估。用户可以通过关注某些学科领域的顶尖人物而持续追踪该领域的学科进展和研究前沿。经过近期的数据扩容，当前同舟云学术共收录了国内外主流学术期刊6万余种，收集的期刊论文及会议论文总量共计约1.5亿篇，并以每天添加12000余篇中外论文的速度递增。我们也可以为用户提供个性化、定制化的学者数据。欢迎来电咨询！咨询电话：010-8811{复制后删除}0370

www.globalauthorid.com

TOP

Copyright © 2019-2024 北京同舟云网络信息技术有限公司
京公网安备11010802033243号京ICP备18003416号-3