A simple and high-yield route to iridium, rhodium, osmium and ruthenium nido-6-metalladecaborane compounds-Reference-Cited by-同舟云学术

A simple and high-yield route to iridium, rhodium, osmium and ruthenium nido-6-metalladecaborane compounds

Published:2021 Issue:45 Volume:50 Page:16751-16764
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Bould Jonathan¹²^ORCID,Londesborough Michael G. S.¹^ORCID,Passarelli Vincenzo²^ORCID,Clegg William³^ORCID,Waddell Paul G.³,Cvačka Josef⁴^ORCID,Macías Ramón²^ORCID

Affiliation:

1. Institute of Inorganic Chemistry, Academy of Sciences of the Czech Republic, Husinec-Řež 250 68, Czech Republic

2. Departamento de Química Inorgánica, Instituto de Síntesis Química y Catálisis Homogenea (ISQCH), Universidad de Zaragoza-CSIC, C/Pedro Cerbuna 12, ES-50009 Zaragoza, Spain

3. School of Natural and Environmental Sciences, Newcastle University, Newcastle upon Tyne, NE1 7RU, UK

4. Institute of Organic Chemistry and Biochemistry of the Czech Academy of Sciences, Flemingovo nám. 2, CZ-166 10 Prague 6, Czech Republic

Abstract

Diethyl ether is a convenient solvent for the high-yield preparation of ten-vertex metalladecaboranes that are excellent ‘B-frames’ for the assembly of bimetallic compounds.

Funder

Ministerio de Ciencia, Innovación y Universidades

Grantová Agentura České Republiky

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/DT/D1DT02971A

Reference77 articles.

1. A unique acetylene-induced reductive PPh3→ PH3stripping of phenyl groups from triphenylphosphine ligands bound to a metallaborane ‘B-frame’ matrix

2. Metallaborane reaction chemistry. Part 1. Two interesting closed cluster compounds from the reaction of acetylene with an open nido-6-iridadecaborane

3. R.Macías , in Handbook of Boron Science , 2018 , pp. 81–116

4. Catalytic activity of a large Rhodium metallaborane towards the [2+2+2] cycloaddition of alkynes

5. Bis(diphenylphosphino)acetylene as Bifunctional Ligand in Dicobalt Carbonyl Complexes

Cited by 3 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Rule breaker boron clusters: a new class of hypoelectronic osmaborane clusters [(Cp*Os)₂B_nH_n] (n = 6–10);Chemical Science;2024

2. Simple Route to [PSH][B₉H₁₄] and a Contemporary Study of Its Solid-State Dynamic Behavior;Inorganic Chemistry;2023-08-30

3. Metallaboranes and metallaheteroboranes: An overview of single-cage and condensed polyhedral clusters;Inorganic Chemistry in India;2023