Reactivity of cyano- and isothiocyanatoborylenes: metal coordination, one-electron oxidation and boron-centred Brønsted basicity-Reference-Cited by-同舟云学术

Reactivity of cyano- and isothiocyanatoborylenes: metal coordination, one-electron oxidation and boron-centred Brønsted basicity

Published:2021 Issue: Volume: Page:
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Hagspiel Stephan¹²³⁴⁵,Elezi Dren¹²³⁴⁵,Arrowsmith Merle¹²³⁴⁵^ORCID,Fantuzzi Felipe¹²³⁴⁵^ORCID,Vargas Alfredo⁶⁷⁸⁹¹⁰,Rempel Anna¹²³⁴⁵,Härterich Marcel¹²³⁴⁵,Krummenacher Ivo¹²³⁴⁵,Braunschweig Holger¹²³⁴⁵^ORCID

Affiliation:

1. Institute for Inorganic Chemistry

2. Julius-Maximilians-Universität Würzburg

3. 97074 Würzburg

4. Germany

5. Institute for Sustainable Chemistry & Catalysis with Boron

6. Department of Chemistry

7. School of Life Sciences

8. University of Sussex

9. Brighton BN1 9QJ

10. UK

Abstract

Borylenes of the form (CAAC)(NHC)BY (Y = CN, NCS; CAAC = cyclic alkyl(amino)carbene; NHC = N-heterocyclic carbene) coordinate to group 6 carbonyl complexes via Y, and show reversible boron-centered Brønsted basicity and one-electron oxidation.

Funder

Deutsche Forschungsgemeinschaft

University of Sussex

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior

Alexander von Humboldt-Stiftung

Studienstiftung des Deutschen Volkes

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/SC/D1SC01580J