Oligomeric semiconductors enable high efficiency open air processed organic solar cells by modulating pre-aggregation and crystallization kinetics

Author:

Xia Hao12,Zhang Ying2,Liu Kuan2ORCID,Deng Wanyuan3,Zhu Mengbing1,Tan Hua1ORCID,Fong Patrick W. K.2ORCID,Liu Heng4,Xia Xinxin4,Zhang Miao5ORCID,Dela Peña Top Archie678ORCID,Ma Ruijie2ORCID,Li Mingjie7,Wu Jiaying6ORCID,Lang Yongwen2,Fu Jiehao2,Wong Wai-Yeung5ORCID,Lu Xinhui4ORCID,Zhu Weiguo1ORCID,Li Gang2ORCID

Affiliation:

1. School of Materials Science and Engineering, Jiangsu Engineering Laboratory of Light-Electricity-Heat Energy-Converting Materials and Applications, Jiangsu Collaborative Innovation Center of Photovoltaic Science and Engineering, National Experimental Demonstration Center for Materials Science and Engineering, Changzhou University, Changzhou 213164, China

2. Department of Electronic and Information Engineering, The Hong Kong Polytechnic University, Hung Hum Kowloon, Hong Kong 999077, China

3. State Key Laboratory of Luminescent Materials and Devices, Institute of Polymer Optoelectronic Materials and Devices, South China University of Technology, Guangzhou 510640, China

4. Department of Physics, The Chinese University of Hong Kong, New Territories, Hong Kong 999077, China

5. Department of Applied Biology and Chemical Technology, The Hong Kong Polytechnic University, Hung Hum Kowloon, Hong Kong 999077, China

6. The Hong Kong University of Science and Technology, Function Hub, Advanced Materials Thrust, Nansha 511400, Guangzhou, P. R. China

7. The Hong Kong University of Science and Technology, School of Science, Department of Chemistry, Kowloon, Hong Kong 999077, P. R. China

8. The Hong Kong Polytechnic University, Faculty of Science, Department of Applied Physics, Kowloon, Hong Kong 999077, P. R. China

Abstract

Two novel oligomers boost the 1 cm2 device to achieve a remarkable PCE exceeding 17% using a green solvent in open-air without post-treatment. In-depth in situ & ex situ studies elucidate the mechanisms of action of the oligomers. This work demonstrates effective guidelines for future manufacturing.

Funder

National Natural Science Foundation of China

Priority Academic Program Development of Jiangsu Higher Education Institutions

Science, Technology and Innovation Commission of Shenzhen Municipality

Hong Kong Polytechnic University

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Nuclear Energy and Engineering,Renewable Energy, Sustainability and the Environment,Environmental Chemistry

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