Vacuum ultraviolet photochemistry of sulfuric acid vapor: a combined experimental and theoretical study

Author:

Zhang Cuihong123,Lin Xiaoxiao1ORCID,Tang Xiaofeng1ORCID,Fittschen Christa3ORCID,Hartweg Sebastian4ORCID,Garcia Gustavo A.4ORCID,Long Bo5ORCID,Zhang Weijun1,Nahon Laurent4ORCID

Affiliation:

1. Laboratory of Atmospheric Physico-Chemistry, Anhui Institute of Optics and Fine Mechanics, HFIPS, Chinese Academy of Sciences, Hefei, 230031 Anhui, China

2. Graduate School, University of Science and Technology of China, Hefei, 230026 Anhui, China

3. University Lille, CNRS, UMR 8522, PC2A – Physicochimie des Processus de Combustion et de l’Atmosphère, F-59000 Lille, France

4. Synchrotron SOLEIL, L’Orme des Merisiers, St. Aubin BP 48, 91192 Gif sur Yvette, France

5. School of Materials Science and Engineering, Guizhou Minzu University, Guiyang, 550025 Guizhou, China

Abstract

VUV photoionization of gas-phase H2SO4 has been studied by using i2PEPICO. Three electronic states of H2SO4+ have been prepared and their ionization energies are determined, as well as the adiabatic appearance energy of fragments.

Funder

National Natural Science Foundation of China

Bureau of International Cooperation, Chinese Academy of Sciences

Guizhou Science and Technology Department

Department of Education of Guizhou Province

Chinese Government Scholarship

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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