C1-Symmetric [Ir(C^N1)(C^N2)(N^O)]-tris-heteroleptic Ir(iii)-complexes with a horizontal orientation for efficient near-infrared (NIR) polymer light-emitting diodes (PLEDs)

Author:

Li Wentao1234,Miao Tiezheng1234,Wang Baowen1234,Liu Jiaxiang1234,Lü Xingqiang1234ORCID,Fu Guorui12345,Feng Weixu6784,Wong Wai-Yeung594ORCID

Affiliation:

1. School of Chemical Engineering

2. Northwest University

3. Xi'an 710069

4. China

5. Department of Applied Biology and Chemical Technology and Research Institute for Smart Energy, The Hong Kong Polytechnic University

6. School of Chemistry and Chemical Engineering

7. Northwestern Polytechnical University

8. Xi’an 710029

9. Hung Hom

Abstract

Through doping of the [Ir(C^N1)(C^N2)(N^O)]-tris-heteroleptic Ir(iii)-complex [Ir(iqbt)(ppy)(pic)] (1) or [Ir(iqbt)(ppy)(Br-pic)] (2) into the EML, the preferentially horizontal orientation is beneficial for their high-performance NIR-PLEDs.

Funder

National Natural Science Foundation of China

Research Grants Council, University Grants Committee

Hong Kong Polytechnic University

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry

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