Palladium-catalyzed silylation reaction between benzylic halides and silylboronate-Reference-Cited by-同舟云学术

Palladium-catalyzed silylation reaction between benzylic halides and silylboronate

Published:2016 Issue:32 Volume:52 Page:5609-5612
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Huang Zhi-Dao¹²³⁴,Ding Ran¹²³⁴,Wang Peng⁵⁶⁷⁴,Xu Yun-He¹²³⁴,Loh Teck-Peng¹²³⁴⁸

Affiliation:

1. Department of Chemistry

2. University of Science and Technology of China

3. Hefei

4. China

5. Department of Chemical Engineering and Technology

6. Tianshui Normal University

7. Tianshui

8. Division of Chemistry and Biological Chemistry

Abstract

An efficient Pd-catalyzed silylation reaction of benzylic halides with silylboronate is reported. In this reaction, primary and secondary benzylic halides could react well with silylboronates to afford benzylic silanes. This reaction accommodates a broad substrate scope and proceeds smoothly under very mild reaction conditions. The corresponding products could be obtained in moderate to high yields and with stereospecificity.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2016/CC/C6CC00713A

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